(a) The most electronegative element of Period 2:
In Period 2 (Li, Be, B, C, N, O, F, Ne), electronegativity increases from left to right.
The most electronegative element in this period is Fluorine (F).
(b) The largest atom of Period 3:
In Period 3 (Na, Mg, Al, Si, P, S, Cl, Ar), atomic size decreases from left to right due to increasing nuclear charge.
Therefore, the largest atom in this period is Sodium (Na).
Final Answers:
(a) Fluorine
(b) Sodium