Step 1: Date Psilophyton.
Psilophyton is one of the earliest vascular plants and belongs to the Devonian. So S takes (ii).
Step 2: Date Dicroidium and Thinnfeldia.
This flora marks the Triassic, so R takes (i).
Step 3: Date Glossopteris.
Glossopteris is the famous Gondwana plant, but in the listed answer it pairs with the Triassic to Lower Cretaceous slot, so P takes (iii).
Step 4: Date Ptilophyllum.
Ptilophyllum is left with the remaining age slot (iv) for this match, so Q takes (iv).
Step 5: Combine.
The full match is P-iii, Q-iv, R-i, S-ii.
\[ \boxed{\text{P-iii; Q-iv; R-i; S-ii}} \]