Step 1: Concept Overview:
This question involves associating essential mineral elements with their corresponding deficiency symptoms in plants.
Step 2: Detailed Explanation:
A. Calcium (Ca): As a key structural element in cell walls (calcium pectate), calcium's immobility means deficiency symptoms manifest in young tissues. A primary symptom is the necrosis of young meristems, such as root tips and young leaves. Therefore, A corresponds to III.
B. Zinc (Zn): Crucial for auxin synthesis (a cell elongation hormone), zinc deficiency results in reduced auxin, causing stunted growth and short internodes, leading to a rosette habit. Thus, B corresponds to IV.
C. Manganese (Mn): An enzyme activator and vital for photosynthesis' water-splitting, manganese deficiency induces interveinal chlorosis and necrotic spots. Therefore, C corresponds to I.
D. Nickel (Ni): As a component of urease (essential for urea metabolism), nickel deficiency causes urea to accumulate, leading to leaf tip necrosis. Thus, D corresponds to II.
Step 3: Conclusion:
The correct matches are A-III, B-IV, C-I, D-II, aligning with option (D).