Step 1: Plan the matching.
Recall one key property or use of each halogen compound.
Step 2: Chloroform (a).
On standing in air and light, chloroform slowly oxidises into the poisonous gas phosgene. So $(a)$ goes with $(r)$.
Step 3: DDT (b).
DDT is fat-soluble, which is why it builds up in fatty tissue. So $(b)$ goes with $(p)$.
Step 4: Freon (c).
Freons (CFCs) rise up and cause depletion of the stratospheric ozone layer. So $(c)$ goes with $(s)$.
Step 5: Iodoform (d).
Iodoform was used as an antiseptic because of the iodine it releases. So $(d)$ goes with $(q)$.
Step 6: Collect the pairs.
Putting it together: $(a)-(r),\ (b)-(p),\ (c)-(s),\ (d)-(q)$, which is the second option.
\[ \boxed{(a)-(r),\ (b)-(p),\ (c)-(s),\ (d)-(q)} \]