To solve the given matching question, we need to correctly pair items from List-I with corresponding items in List-II, based on acceptable associations in the field of chemistry. Let's analyze each pair:
Aluminium and Kaolinite: Kaolinite is a clay mineral, typically represented by the chemical formula Al2Si2O5(OH)4, which is a source of aluminium. Therefore, Aluminium matches with Kaolinite (a-iii).
Iron and Siderite: Siderite is iron carbonate (FeCO3) and is an ore of iron. So, Iron correctly matches with Siderite (b-i).
Copper and Malachite: Malachite is a copper carbonate hydroxide mineral (Cu2(CO3)2(OH)2), thus associating Copper with Malachite (c-iv).
Zinc and Calamine: Calamine is a mineral containing zinc, primarily zinc carbonate (ZnCO3) and zinc silicate. Thus, Zinc matches with Calamine (d-ii).
Therefore, the correct option is:
(a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)
This option aligns with the known associations between the metals and their respective ores.