Step 1: Determine the application of each component.
- Rotary atomizer (A) is employed in atomization, which typically involves centrifugal energy (2).
- Relative volatility (B) is a key factor in distillation (3).
- Pneumatic nozzle (C) utilizes kinetic energy (1) for atomizing or injecting fluids.
- Selectivity (D), in liquid-liquid extraction (4), refers to the preferential uptake of a solute by a solvent.
Final Answer: \[ \boxed{A - 2, B - 3, C - 1, D - 4} \]