Concept:
Use principal value ranges:
\[
\sec^{-1}x \in [0,\pi],\ x\neq 0
\quad,\quad
\cosec^{-1}x \in \left[-\frac{\pi}{2},\frac{\pi}{2}\right], x\neq 0
\]
Step 1: {Evaluate $\sec^{-1}(-2)$.}
\[
\sec \theta = -2 \Rightarrow \cos\theta = -\frac{1}{2}
\Rightarrow \theta = \frac{2\pi}{3}
\]
Step 2: {Evaluate $\cosec^{-1}(-\sqrt{2})$.}
\[
\csc\theta = -\sqrt{2} \Rightarrow \sin\theta = -\frac{1}{\sqrt{2}}
\Rightarrow \theta = -\frac{\pi}{4}
\]
Step 3: {Evaluate $\cosec^{-1}(2)$.}
\[
\sin\theta = \frac{1}{2} \Rightarrow \theta = \frac{\pi}{6}
\]
Step 4: {Evaluate $\sec^{-1}\left(-\frac{2}{\sqrt{3}}\right)$.}
\[
\cos\theta = -\frac{\sqrt{3}}{2}
\Rightarrow \theta = \frac{5\pi}{6}
\]