Each chemical here belongs to a distinct pesticide group, so the fastest method is to recall the group each one is classified under. Thiophanate-methyl belongs to the benzimidazole group of fungicides, used to control fungal infections in crops, which links it to Fungicide. Atrazine is a well known triazine-group herbicide sprayed to control weeds, linking it to Weedicide. Fenamiphos is an organophosphate compound applied to soil to control nematodes, linking it to Nematicide. Afidopyropen is a newer pyropene-class chemical developed to control aphids and other sucking insects, linking it to Insecticide. Putting these four links together gives (A)-(III), (B)-(I), (C)-(IV), (D)-(II). \[\boxed{\text{Option 2}}\]