To test validity of these predicate-logic statements, use a small two-element domain $\{a, b\}$ and try every combination of truth values for $P(a)$ and $P(b)$. If any single combination makes a statement false, the statement is not valid; if every combination makes it true, it is valid.
Running through all four truth-value combinations on a small domain shows the same answer as picking targeted counterexamples: option (A) survives every combination, while (B), (C) and (D) each fail for at least one assignment of $P(a)$ and $P(b)$.
Let's summarize:
The statements that are NOT valid are (B), (C) and (D).