Step 1: Think of it as a pigeonhole problem.
Every state reachable in the determinized version of $M$ (built by tracking the exact set of NFA states the automaton could currently be in) is labelled by a subset of $M$'s 6 states. There are only $2^6 = 64$ distinct subsets that exist at all, so no matter how $M$'s transitions are wired, the determinized automaton can never be forced to use more than 64 distinct labels/states. This is a pigeonhole ceiling, not a typical-case estimate -- it is absolute.
Step 2: Minimality only removes states, it never adds them.
Minimization works by collapsing states of a DFA that are behaviourally indistinguishable (same accept/reject outcome for every possible future input) into a single state. Starting from at most 64 states and only ever merging some of them together can only bring the count down to somewhere between 1 and 64; it is structurally impossible to end up with more states after minimization than before it.
Step 3: Screen the four candidate counts against the ceiling of 64.
32 is comfortably below 64, so there is no obstruction to a suitably designed 6-state NFA needing exactly 32 states after minimization.
1 is the smallest possible DFA size and is trivially reachable (e.g. an NFA that accepts every string, or one that accepts no string, minimizes to a single state).
65 is one more than the ceiling of 64, so it is unreachable under any circumstances.
128 equals $2^7$, which would be the ceiling for a 7-state NFA, not a 6-state one; for $n=6$ it overshoots the true ceiling of 64 by double, so it is also unreachable.
Step 4: State the impossible set.
$\[ \boxed{\text{65 and 128 (options B and D) can never be the minimal DFA size for a 6-state NFA}} \]$