Given the matrix \( A = \begin{bmatrix} 2 & a & 0 \\ 1 & 3 & 1 \\ 0 & 5 & b \end{bmatrix} \) and the equation \( A^3 = 4A^2 - A - 21I \), where \( I \) is the \( 3 \times 3 \) identity matrix, we aim to determine the value of \( 2a + 3b \).
We will expand the given equation to derive conditions for \( a \) and \( b \).
Therefore, \( 2a + 3b = -13 \). The correct answer is -13.