Each of the three painted faces of the big cube is a 7 by 7 grid of unit-cube faces, but some of those unit cubes also touch a second painted face along a shared edge, and those must be excluded from the "exactly one colour" count.
Wait, checking this more carefully by direct coordinates is safer than the edge-count method: fixing one coordinate at 7 and requiring the other two strictly between 1 and 6 already avoids both shared edges of that face by construction, so each face directly gives $6 \times 6 = 36$ single-coloured cubes without extra adjustment.
With 3 faces: $3 \times 36 = 108$.
So the correct answer is option A, 108.


