Step 1: Find the full circumference first.
For radius $32$ cm, the whole circumference is $2\pi r = 2\pi(32)=64\pi$ cm.
Step 2: Work out what fraction of the full circle the arc represents.
An angle of $45^\circ$ out of the full $360^\circ$ is $\frac{45}{360}=\frac18$ of one complete revolution.
Step 3: Take that fraction of the circumference.
Arc length $=\frac18\times64\pi = 8\pi$ cm.
\[ \boxed{8\pi \text{ cm}} \]