A light-harvesting molecule must be a pigment that sits in the photosynthetic membrane and absorbs visible light to pass energy toward the reaction centre.
Vitamin D and cytochrome C have no such role -- vitamin D is an animal steroid precursor, and cytochrome C is an electron-transfer protein in respiration. Anthocyanins are vacuolar pigments that colour flowers and fruits but do not feed energy into photosynthesis.
Chlorophyll and carotenoids are the two pigment classes that genuinely sit in the thylakoid membrane and harvest light for photosynthesis, so this pairing fits the definition.
A useful way to confirm this is to think in terms of the visible-light spectrum and which pigments plug the gaps in each other's absorption.
Because chlorophyll and carotenoids together cover complementary parts of the visible spectrum used in photosynthesis, this is the pairing that functions as the light-harvesting system.
So, the correct answer is Chlorophyll and carotenoid.
