Step 1: Use the closing condition.
Given $\vec a+\vec b+\vec c=0$, so $\vec a=-(\vec b+\vec c)$.
Step 2: Take magnitudes squared.
Then $|\vec a|^2=|\vec b+\vec c|^2$.
Step 3: Expand the right side.
Let $\theta$ be the angle between $\vec b$ and $\vec c$. Then \[ |\vec b+\vec c|^2=|\vec b|^2+|\vec c|^2+2|\vec b||\vec c|\cos\theta. \] Step 4: Substitute the magnitudes.
With $|\vec a|=7$, $|\vec b|=5$, $|\vec c|=3$: \[ 49=25+9+2(5)(3)\cos\theta. \] Step 5: Solve for $\cos\theta$.
So $49=34+30\cos\theta$, giving $30\cos\theta=15$, hence $\cos\theta=\dfrac{1}{2}$.
Step 6: Read off the angle.
Therefore $\theta=60^\circ$.
\[ \boxed{60^\circ} \]