Step 1: Understand the problem setup.
We need points on the line $x + y = 4$ that are at a unit distance from the line $4x + 3y - 10 = 0$. We must find the distance between these two points.
Step 2: Parametrise points on $x + y = 4$.
Any point on $x + y = 4$ can be written as $(t, 4 - t)$ for some real $t$.
Step 3: Apply the distance condition.
The distance from $(t, 4-t)$ to $4x + 3y - 10 = 0$ is \[ \frac{|4t + 3(4-t) - 10|}{\sqrt{16 + 9}} = \frac{|4t + 12 - 3t - 10|}{5} = \frac{|t + 2|}{5}. \] Set this equal to 1: \[ |t + 2| = 5. \]
Step 4: Solve for $t$.
\[ t + 2 = 5 \Rightarrow t = 3, \quad \text{or} \quad t + 2 = -5 \Rightarrow t = -7. \]
Step 5: Find the two points.
For $t = 3$: point is $(3, 1)$. For $t = -7$: point is $(-7, 11)$.
Step 6: Compute the distance between the two points.
\[ d = \sqrt{(3 - (-7))^2 + (1 - 11)^2} = \sqrt{100 + 100} = \sqrt{200} = 10\sqrt{2}. \]
\[ \boxed{10\sqrt{2}} \]