Concept: A homogeneous system has a non-trivial solution only when the determinant of its coefficient matrix is zero.
Step 1: Form the determinant and simplify to obtain \(2-2\cos2\theta-\sin3\theta=0\). Using \(1-\cos2\theta=2\sin^2\theta\), this becomes \(4\sin^2\theta=\sin3\theta\).
Step 2: Substituting \(\sin3\theta=3\sin\theta-4\sin^3\theta\) gives \(4\sin^2\theta+4\sin\theta-3=0\). Let \(s=\sin\theta\). Then \((2s-1)(2s+3)=0\), so \(s=\frac12\).
Step 3: Hence, \(\theta=\frac{\pi}{6},\frac{5\pi}{6}\), giving \(\left|\theta_1-\theta_2\right|=\boxed{\frac{2\pi}{3}}\).