Step 1: Reduce the system by elimination.
Take the equations \( x+y+z=2 \), \( 2x+y-z=3 \) and \( 3x+2y+kz=4 \). Subtracting twice the first equation from the second and three times the first from the third removes \( x \) from the last two rows, giving
\[ -y-3z=-1 \quad \text{and} \quad -y+(k-3)z=-2 \]
Step 2: Eliminate \( y \) as well.
Subtracting these two reduced equations removes \( y \), leaving a single equation in \( z \):
\[ kz = -1 \]
Step 3: Decide when this gives one value of \( z \).
This equation has a unique solution for \( z \) only when its coefficient is non-zero. If \( k = 0 \), the equation becomes \( 0 = -1 \), which is impossible, so a unique solution fails exactly when \( k = 0 \).
\[ \boxed{k \neq 0} \]