Point \( A \) is the intersection of lines \( AB \) and \( AC \). The equation of the line passing through \( A \) is:
\[
(x + 2y - 1) + \lambda (2x + 3y - 1) = 0
\]
This line passes through the orthocenter \( (0,0) \). Substituting \( (0,0) \):
\[
-1 + \lambda (-1) = 0
\]
\[
-1 - \lambda = 0
\]
\[
\lambda = -1
\]
Substituting \( \lambda = -1 \) into the equation yields:
\[
x + y = 0
\]
Therefore, the equation of \( AD \) is:
\[
x + y = 0
\]
Since \( AD \perp BC \):
\[
\frac{-1 - x}{a} = \frac{d}{b} = -1
\]
This simplifies to:
\[
a + b = 0
\]
Similarly, applying the condition \( BE \perp CA \) yields:
\[
a + 2b = 8
\]
Solving the system of equations (3) and (4):
\[
a + b = 0
\]
\[
a + 2b = 8
\]
Subtracting Eq. (3) from Eq. (4):
\[
(a + 2b) - (a + b) = 8 - 0
\]
\[
b = 8
\]
Substituting \( b = 8 \) into Eq. (3):
\[
a + 8 = 0
\]
\[
a = -8
\]
The values are:
\[
a = -8, \quad b = 8
\]