The volume function is given by \( V = \frac{1}{4}(Sx - 2x^3) \). Differentiating \( V \) with respect to \( x \) yields \( \frac{dV}{dx} = \frac{1}{4}\left( S - 6x^2 \right) \). To find the value of \( x \) that maximizes \( V \), we set \( \frac{dV}{dx} = 0 \): \( S - 6x^2 = 0 \), which simplifies to \( x^2 = \frac{S}{6} \), so \( x = \frac{\sqrt{S}}{\sqrt{6}} \). Therefore, the volume is maximized when \( x = \frac{\sqrt{6}}{6} \).