Step 1: Use the pairing property of an AP.
In an AP, terms equally spaced from the two ends add to the same value; in particular $a_1+a_{10}=a_2+a_9=\dots$, and this common sum equals twice the average term.
Step 2: Use the given sum to find that average.
Since $S_{10}=0$, the average of the 10 terms is $0$, so $a_1+a_{10}=0$.
Step 3: Solve for $a_{10}$.
Since $a_1=a$, we get $a_{10}=-a$, matching option (C).
\[ \boxed{a_{10}=-a} \]