Step 1: Plan:
Apply L'Hopital's rule, because the form is $\frac00$.
Step 2: Steps:
Differentiate top and bottom: $\frac{8^x\ln8 - 2^x\ln2}{k^x\ln k}$. At $x = 0$ this is $\frac{\ln8-\ln2}{\ln k} = \frac{\ln4}{\ln k}$.
Set it equal to $2$: $\ln k = \ln 2$, so $k = 2$.
Final Answer:
The value of $k$ is $2$, option (D).
\[ \boxed{2} \]