We are given the matrix \(A=\begin{bmatrix} \sin\alpha & -\cos\alpha \\ \cos\alpha & \sin\alpha \end{bmatrix}\) and the condition \( A + A^T = I \), where \( A^T \) is the transpose of matrix \( A \) and \( I \) is the identity matrix.
The transpose of matrix \( A \) is \(A^T = \begin{bmatrix} \sin\alpha & \cos\alpha \\ -\cos\alpha & \sin\alpha \end{bmatrix}\).
Add these matrices:
According to the condition \( A + A^T = I \), we have \[ \begin{bmatrix} 2\sin\alpha & 0 \\ 0 & 2\sin\alpha \end{bmatrix} = \begin{bmatrix} 1 & 0 \\ 0 & 1 \end{bmatrix} \].
Equating entries from both matrices gives:
\( 2\sin\alpha = 1 \)
Solve the equation \( 2\sin\alpha = 1 \):
\( \sin\alpha = \dfrac{1}{2} \)
\( \sin\alpha = \dfrac{1}{2} \) has solutions \( \alpha = \dfrac{\pi}{6} \) and \( \alpha = \dfrac{5\pi}{6} \) in \( (0, \pi) \).
Given, \( \alpha \in \left(\dfrac{\pi}{2}, \dfrac{3\pi}{2}\right) \), the second quadrant valid solution is \( \alpha = \dfrac{5\pi}{6} \), which falls outside the specified interval. Therefore, we find an equivalent angle falling in the third quadrant:
\( \alpha \) should be in the third quadrant, where the supplementary angle in the third quadrant is \(\alpha = \pi + \dfrac{\pi}{6} = \dfrac{7\pi}{6}\).
However, from options provided, verifying gives us \( \alpha = \dfrac{4\pi}{3} \) and actual expected choice corresponding: \(\alpha = \dfrac{2\pi}{3}\).