Step 1: Write the matrix from the rule.
The rule gives zero when the row and column numbers differ, and $i+j = 2i$ on the diagonal. So the diagonal is $2,4,6$ and the matrix is $\operatorname{diag}(2,4,6)$.
Step 2: Use the nesting of matrix types.
A unit matrix is a scalar matrix, and a scalar matrix is a diagonal matrix. Our matrix has different diagonal entries. So it is diagonal, but it is neither scalar nor unit. This makes B true, A and C false.
Step 3: Test symmetry.
The transpose of a diagonal matrix has the same entries, because moving $(i,j)$ to $(j,i)$ only touches zero places. So $A^T=A$ and D is true.
Step 4: Choose the option.
The correct pair is B and D, which is option 3.
Step 5: Why the other options fail.
Option 1 has C, and C is false because the diagonal is 2, 4, 6 and not all ones. Option 2 has A and C, and both are false. Option 4 also has C. Only option 3 has exactly the two true statements B and D. Note that a matrix like $2I$ would be scalar, but $\operatorname{diag}(2,4,6)$ is not, because its entries are unequal.
Final Answer:
The correct statements are B and D.
\[ \boxed{\text{Option 3}} \]