Step 1: Bring in the triple-angle identity.
Replace $\sin 3\theta$ using $\sin 3\theta = 3\sin\theta - 4\sin^3\theta$ in the equation $3\sin\theta = 2\sin 3\theta$.
Step 2: Substitute.
$3\sin\theta = 2(3\sin\theta - 4\sin^3\theta) = 6\sin\theta - 8\sin^3\theta$.
Step 3: Move everything to one side.
$8\sin^3\theta - 3\sin\theta = 0$.
Step 4: Factor out the common term.
$\sin\theta\,(8\sin^2\theta - 3) = 0$, giving $\sin\theta = 0$ or $\sin^2\theta = \dfrac{3}{8}$.
Step 5: Reject the invalid root.
Since $0 < \theta < \pi$, $\sin\theta = 0$ is not allowed (it would force $\theta = 0$ or $\pi$), so we keep $\sin^2\theta = \dfrac{3}{8}$.
Step 6: Take the positive root.
On $(0,\pi)$, $\sin\theta > 0$, so $\sin\theta = \sqrt{\dfrac{3}{8}} = \dfrac{\sqrt{3}}{2\sqrt{2}} = \dfrac{3}{2\sqrt{2}}$ in the given form, which is option 2 and agrees with the key.
\[ \boxed{\sin\theta = \dfrac{3}{2\sqrt{2}}} \]