Question:medium

Identify the following terms / compounds:
(a) A compound which reacts with water to give acetylene gas.
(b) The gas evolved when sodium propanoate is heated with soda lime.
(c) A reddish-brown precipitate formed when ferric chloride solution reacts with an alkali.
(d) A pair of electrons present in an atom which is not shared with any other atom during bond formation.
(e) The relative molecular mass of a substance expressed in grams.

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When using soda lime for decarboxylation, the resulting alkane always has one carbon atom less than the starting carboxylic acid salt. This is why sodium propanoate (C_3) yields ethane (C_2).
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Solution and Explanation

(a) The compound is calcium carbide (CaC2).
It reacts with water to produce acetylene gas.

(b) The gas evolved is ethane (C2H6).
Sodium propanoate on heating with soda lime undergoes decarboxylation and forms ethane.

(c) The reddish-brown precipitate is ferric hydroxide [Fe(OH)3].

(d) The pair of electrons is called a lone pair of electrons or non-bonding electron pair.

(e) The relative molecular mass of a substance expressed in grams is called gram molecular mass or molar mass.
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