Question:easy

Identify the factor responsible for colour of transition metal compounds.

Show Hint

Partly filled d orbitals split in a ligand field and absorb visible light for d-d jumps.
Updated On: Oct 1, 2026
  • d-d transitions
  • s-p mixing
  • Ionisation
  • Shielding effect
Show Solution

The Correct Option is A

Solution and Explanation

Step 1: Orbital splitting:
Ligands split the d orbitals by an energy gap $\Delta$, which for many complexes matches visible light.

Step 2: Absorption:
An electron absorbs a photon with energy equal to $\Delta$ and moves up, so the compound shows the complementary colour.

Step 3: Check with exceptions:
$d^0$ and $d^{10}$ ions have no d-d jump and are colourless. So the cause is d-d transitions, option (A).

Final Answer:
Colour arises from d-d transitions. \[ \boxed{\text{(A) }d\text{-}d\ \text{transitions}} \]
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