Question:medium

Identify the correct trend of acidic strength for the given alcohols

Show Hint

The acidity of alcohols decreases with increasing alkyl substitution because alkyl groups show a \(+I\) effect and destabilize the alkoxide ion. \[ 1^\circ \text{ alcohol} \gt 2^\circ \text{ alcohol} \gt 3^\circ \text{ alcohol} \] in acidic strength.
Updated On: Jun 26, 2026
  • \((i)\gt (iii)\gt (ii)\)
  • \((i)\gt (ii)\gt (iii)\)
  • \((iii)\gt (i)\gt (ii)\)
  • \((iii)\gt (ii)\gt (i)\)
Show Solution

The Correct Option is B

Solution and Explanation

Step 1: Recall the effect of alkyl groups on alcohol acidity.
Acidity of alcohols decreases as the number of alkyl groups on the carbon bearing -OH increases. Alkyl groups destabilise the alkoxide ion by induction (+I effect), making the alcohol less acidic.

Step 2: Apply the trend.
Primary alcohol (fewest alkyl groups) is most acidic, secondary less, tertiary least. So: (i) primary > (ii) secondary > (iii) tertiary. \[ oxed{(i) \gt (ii) \gt (iii)} \]
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