Step 1: Recall what makes a molecule chiral.
A molecule is chiral if it cannot be superimposed on its mirror image. The simplest sign is a carbon bonded to four different groups, called a stereocentre.
Step 2: Set the checking rule.
For each structure, look for at least one carbon that carries four different attachments. If such a carbon exists and the molecule has no internal symmetry that cancels it, the molecule is chiral.
Step 3: Examine the structures one by one.
Going through the given structures I to V, we test each carbon to see whether all four groups around it differ.
Step 4: Mark the chiral ones.
Structures I, IV and V each have a carbon with four different groups, so they are chiral.
Step 5: Reject the others.
The remaining structures either lack a four different group carbon or have a symmetry that makes them achiral, so they are not chiral.
Step 6: State the answer.
The chiral molecules are I, IV and V.
\[ \boxed{\text{I, IV, V only}} \]