Question:medium

Identify metal halide from following having highest ionic character? (M = metal atom)

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Fajan's Rules made simple: Small cation + Large anion = Highly Covalent. Large cation + Small anion = Highly Ionic. Fluorine is the smallest anion, so it almost always forms the most ionic compounds!
Updated On: Jun 8, 2026
  • MF
  • MBr
  • MI
  • MCl
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The Correct Option is A

Solution and Explanation

Step 1: What we compare.
The metal $M$ is the same in every option, so only the halogen changes. We compare $F$, $Cl$, $Br$ and $I$.
Step 2: The guiding idea.
Fajan's rules say a bond becomes more covalent when the negative ion is big and easily distorted, and more ionic when the negative ion is small and holds its electrons tightly.
Step 3: Compare the sizes.
Going down the halogens the ions grow in size, $F^- < Cl^- < Br^- < I^-$. So iodide is the largest and fluoride is the smallest.
Step 4: Apply to covalent character.
The big iodide ion is easily pulled out of shape, so $MI$ is the most covalent.
Step 5: Apply to ionic character.
The tiny fluoride ion holds its electrons firmly and resists distortion, so $MF$ is the most ionic.
Step 6: Final choice.
The halide with the highest ionic character is $MF$, which is option 1.
\[ \boxed{MF} \]
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