Step 1: Read n.
The value $n = 4$ tells us the orbital is in the fourth shell.
Step 2: Read l.
The value of $l$ sets the subshell: 0 is s, 1 is p, 2 is d, 3 is f. Here $l = 3$, so it is an f subshell.
Step 3: Combine.
Fourth shell plus f subshell gives a 4f orbital, and $m = 0$ is a valid orientation for it.
\[ \boxed{\text{4f, option 1}} \]