Step 1: Group the vaccine. DPT, DT, TT, and Hepatitis B are the freeze-sensitive vaccines that lose potency if frozen, while OPV and measles tolerate deep freezing.
Step 2: Because DPT is freeze-sensitive, the safe zone at the peripheral level of the cold chain is the refrigerator compartment held at 4 to 8 degree C.
Step 3: Eliminate the others. Room temperature is unsafe heat exposure, and a 0 to -20 degree C freezer would solidify and inactivate DPT.
\[\boxed{4 \text{ to } 8\ ^{\circ}\text{C}}\]