Question:medium

How many isomers are possible for C$_4$H$_8$Cl$_2$ (including chain and positional)?

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Consider both chain and positional isomerism when calculating the number of possible isomers.
Updated On: Mar 28, 2026
  • 6
  • 8
     

  • 7
     

  • 9
Show Solution

The Correct Option is B

Solution and Explanation

Isomer Count for \( \text{C}_4\text{H}_8\text{Cl}_2 \)

Isomer Classifications:

  • Structural isomers based on carbon skeleton arrangement (e.g., n-butane vs. isobutane)
  • Positional isomers detailing chlorine atom locations

1. Derived from n-butane (straight-chain):

Chlorine atom placement possibilities:

  • 1,1-dichlorobutane
  • 1,2-dichlorobutane (vicinal)
  • 1,3-dichlorobutane
  • 2,2-dichlorobutane
  • 2,3-dichlorobutane

Subtotal = 5 isomers

 

2. Derived from isobutane (branched-chain):

Chlorine atom placement possibilities:

  • 1,1-dichloro-2-methylpropane
  • 1,2-dichloro-2-methylpropane
  • 2,2-dichloro-2-methylpropane

Subtotal = 3 isomers

 

✅ Consolidated Result:

\[ \boxed{8\ \text{isomers}} \]

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