Stage 1: Problem Definition.
A web server handles a high volume of requests (thousands) but has a limited processing capacity (100 concurrent requests). Incoming requests exceeding this capacity are placed in a waiting line.
Stage 2: Data Structure Characteristics.
- Stack: Last-In, First-Out (LIFO) principle, not suitable for equitable request handling.
- Queue: First-In, First-Out (FIFO) principle, guarantees requests are processed in their arrival sequence.
- List: A general collection, but offers no inherent order for request processing.
- Dictionary: Designed for key-value associations, not optimized for managing request order.
Stage 3: Optimal Solution.
Given the requirement for processing requests strictly by arrival order, a Queue is the most fitting data structure.
Conclusion: \[\boxed{\text{Queue}}\]