Step 1: State the test.
A function is strictly increasing wherever its derivative $f'(x)$ is positive, so we differentiate $f(x) = e^{-1/x}$.
Step 2: Note the domain restriction.
The term $\dfrac{1}{x}$ is undefined at $x = 0$, so $x = 0$ is excluded from the start.
Step 3: Differentiate with the chain rule.
$f'(x) = e^{-1/x}\cdot \dfrac{d}{dx}\!\left(-\dfrac{1}{x}\right)$. Since $\dfrac{d}{dx}\!\left(-\dfrac{1}{x}\right) = \dfrac{1}{x^2}$, we get $f'(x) = \dfrac{e^{-1/x}}{x^2}$.
Step 4: Sign of the numerator.
$e^{-1/x}$ is an exponential, which is always positive for every allowed $x$.
Step 5: Sign of the denominator.
$x^2 > 0$ for every $x \neq 0$.
Step 6: Combine the signs.
A positive over a positive is positive, so $f'(x) > 0$ for all $x \neq 0$. Hence $f$ is strictly increasing for every non-zero real number, which is option 4 and matches the key.
\[ \boxed{x \in \mathbb{R}\setminus\{0\}} \]