Step 1: Look at what happens during SI cold starting.
At low temperature the fuel does not evaporate well, so a rich, easily vaporized fuel is needed to form a combustible charge.
The property that controls this is volatility: a more volatile fuel starts easier in the cold.
Step 2: Look at what controls ignition delay in a CI engine.
In a CI engine fuel is sprayed into hot compressed air and must self-ignite after a short delay.
Cetane number measures how readily the fuel self-ignites, so a low cetane number means a long ignition delay and rough running.
Final Answer:
P is volatility (SI cold starting) and Q is cetane number (CI ignition delay), so the pair matches option (B).
\[ \text{P = Volatility}, \ \text{Q = Cetane number} \]