Step 1: Identify the branches:
Branch 1 has C1, C2, C3 in series. Branch 2 is C4 alone. They are in parallel across V, so both branches have voltage V.
Step 2: Charge on branch 1:
The equivalent capacitance of branch 1 is $\left(\frac1C + \frac1{2C} + \frac1{3C}\right)^{-1} = \frac{6C}{11}$. Its charge is $\frac{6C}{11}V$, and this same charge sits on C2.
Step 3: Charge on C4:
$Q_4 = (4C)V$.
Step 4: Divide:
$\frac{Q_2}{Q_4} = \frac{6/11}{4} = \frac{6}{44} = \frac{3}{22}$.
Final Answer:
The ratio is 3/22.
\[ \boxed{\frac{3}{22}} \]