
A useful way to check this is to notice, before doing any node-voltage algebra, that every path from Y or Z back to the reference node W passes only through ideal voltage sources, never through a resistor alone.
From Y, the only way back to W without crossing a resistor first is Y to X (ideal 20 V source) then X to W (ideal 100 V source). Both are ideal sources, so this path fixes $V_Y$ completely, with zero equivalent resistance along it.
From Z, the direct path to W is the ideal 20 V source between Z and W, again with zero resistance.
Since both terminal nodes of interest, Y and Z, are each rigidly fixed by an unbroken chain of ideal sources back to ground, their difference $V_Y-V_Z$ can never be perturbed by any external load connected across Y-Z, no matter how much current that load draws. This is exactly the condition for a zero Thevenin resistance: $R_{TH}=0\,\Omega$.
Now compute the fixed node voltages: $V_X=100$ V (from the X-W source), so $V_Y=V_X+20=120$ V (from the X-Y source). And $V_Z=-20$ V (from the Z-W source, oriented so that W is 20 V above Z).
The open-circuit voltage is:
\[ V_{TH}=V_Y-V_Z=120-(-20)=140\text{ V} \]Combined with the zero-resistance argument above:
\[ \boxed{V_{TH}=140\text{ V},\ R_{TH}=0\ \Omega} \]