For an ideal gas, a cyclic process ABCA as shown in the P–T diagram. When represented in P–V plot, it would be
\( \text{M} \xrightarrow{\text{CH}_3\text{MgBr}} \text{N} + \text{CH}_4 \uparrow \xrightarrow{\text{H}^+} \text{CH}_3\text{COCH}_2\text{COCH}_3 \)
Identify the ion having 4f\(^6\) electronic configuration.