For any ideal gas, the ratio of work done at constant pressure to heat at constant volume is matching the degree factor: $\frac{W}{Q_v} = \frac{R}{C_v}$. Since $C_v = 1.5R$ for a monoatomic gas, the work is roughly $\frac{2}{3}$ of the internal energy, making $Q_v = 1.5W$ instantly!