Concept:
For a cell of emf \(E\), terminal potential difference \(V\), current \(I\), and internal resistance \(r\):
During discharging,
\[
V=E-Ir
\]
During charging,
\[
V=E+Ir
\]
Step 1:Check statement (A).
When the cell is not connected externally,
\[
I=0
\]
Therefore,
\[
V=E
\]
Hence,
\[
{\text{Statement (A) is true.}}
\]
Step 2: Check statement (B).
During discharging,
\[
V=E-Ir
\]
which implies
\[
V<E
\]
or
\[
E>V
\]
Thus emf is greater than the terminal potential difference.
Hence,
\[
{\text{Statement (B) is false.}}
\]
Step 3: Check statement (C).
When discharging,
\[
E>V
\]
but when the cell is open,
\[
E=V
\]
Therefore emf is not always greater than terminal voltage.
Hence,
\[
{\text{Statement (C) is false.}}
\]
Step 4: Check statement (D).
During charging,
\[
V=E+Ir
\]
Therefore,
\[
V>E
\]
or
\[
E<V
\]
Hence emf is less than the terminal potential difference.
\[
{\text{Statement (D) is true.}}
\]
Step 5: State the answer.
\[
{
\text{Statements (A) and (D) are correct.}
}
\]
Hence, the correct option is
\[
{(A)}
\]