Step 1: List the days.
Five boys play on five days from Tuesday to Saturday, one boy per day.
Step 2: Write the clues.
Nayan plays right after Sameer. Exactly two people play between Ajay and Sameer. Vijay plays the day right before Mohit.
Step 3: Place Ajay and Sameer.
If Ajay plays on Tuesday, then with two people between them Sameer plays on Friday. Then Nayan, who is right after Sameer, plays on Saturday.
Step 4: Fit Vijay and Mohit.
The free days now are Wednesday and Thursday. Vijay must come right before Mohit, so Vijay plays Wednesday and Mohit plays Thursday.
Step 5: Final arrangement.
Ajay Tuesday, Vijay Wednesday, Mohit Thursday, Sameer Friday, Nayan Saturday. All clues are satisfied.
Step 6: Read the answer.
The person on Saturday is Nayan. Note the given key marks Mohit, but the correct fit here is Nayan, which also matches the question's own solution.
Answer: Nayan