Step 1: Eliminate
Glycine with amino caproic acid gives Nylon-2-nylon-6.
Step 2: Check the others
Options with alpha-hydroxy or caproic acid do not match the name PHBV.
Step 3: Conclude
The name has hydroxybutyrate and hydroxyvalerate parts, both at the beta position, so the first option fits.
Final Answer:
PHBV is formed from the two beta-hydroxy acids.
\[ \boxed{\text{(A) }\beta\text{-hydroxy butyric acid and }\beta\text{-hydroxy valeric acid}} \]