Step 1: The dangerous effects of a scorpion sting come from an autonomic catecholamine surge that loads the heart and floods the lungs.
Step 2: Blocking the alpha-1 receptor unloads the heart and clears pulmonary oedema, and the agent that does this is prazosin, making it the pharmacological drug of choice.
Step 3: Antivenom immunotherapy, midazolam for agitation and aspirin may supplement therapy according to severity, but they sit alongside prazosin rather than replacing it.
Step 4: The remaining options - EDTA, neostigmine and N-acetylcysteine - are antidotes for unrelated toxins, so prazosin is the answer.
\[\boxed{\text{Prazosin}}\]