Question:medium

Determine the empirical formula of an oxide of iron, which has 69.9% iron and 30.1% dioxygen by mass.

Updated On: Jan 21, 2026
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Solution and Explanation

% of iron by mass = 69.9 % [Given] 
% of oxygen by mass = 30.1 % [Given]
Relative moles of iron in iron oxide:

\(=\frac{ \% \text{of iron by mass} }{ \text{Atomic mass of iron}}\)

\(= \frac{69.9 }{ 55.85}\)= 1.25

Relative moles of oxygen in iron oxide:

\(= \frac{\% \text{of oxygen by mass} }{ \text{Atomic mass or oxygen}}\)

\(= \frac{30.1 }{ 16.00}\)

= 1.88
Simplest molar ratio of iron to oxygen:
\(= 1.25\ratio 1.88\)
\(= 1\ratio 1.5\)
\(≈2\ratio 3\)
∴ The empirical formula of the iron oxide is \(\text{Fe}_2\text{O}_3\).

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