Step 1: Define primary and secondary pollutants.
A primary pollutant is emitted directly from a source, a secondary pollutant is formed afterwards by a chemical reaction in the atmosphere.
Step 2: Classify each of the four options.
NO comes straight out of vehicle and combustion exhaust, $\mathrm{SO_2}$ comes directly from burning sulphur containing fuel, and soot is directly emitted particulate matter, all three are primary.
Step 3: Look at ozone separately.
Ground level $\mathrm{O_3}$ is not emitted by any source, it forms when NO and volatile organic compounds react in sunlight, so it is the secondary pollutant among the four.
\[ \boxed{\mathrm{O_3}} \]