Instead of directly guessing the answer, build it by comparing $T$ to the plane function $x+y$ using the maximum principle for harmonic functions.
Define $w(x,y) = T(x,y) - (x+y)$. Since $x+y$ is harmonic (linear functions always satisfy Laplace's equation, as their second partial derivatives are zero), and $T$ is harmonic by the problem statement, the difference $w$ is also harmonic on the square, being a difference of two harmonic functions.
Now check what $w$ looks like on each edge of the square, using the given boundary values of $T$:
So $w$ is harmonic on the whole square and equals $0$ on all four edges of the boundary. By the maximum principle, a harmonic function attains both its maximum and minimum on the boundary of the region. Since $w$ is $0$ everywhere on the boundary, its maximum and minimum are both $0$, which forces $w(x,y)=0$ at every point inside the square too.
This means $T(x,y) - (x+y) = 0$ for all $(x,y)$ in the square, so $T(x,y) = x+y$ everywhere.
Let's summarize:
So the value of $T(1/2, 1/3)$ is $5/6$.
\[\boxed{T(1/2,1/3) = \dfrac{5}{6}}\]