Question:medium

Consider the following reaction: \[ xMnO_4^- + yI^- + zH^+ \rightarrow pMn^{2+} + qIO_3^- + rH_2O \] The correct ratio \(x:y\) in the balanced equation is:

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In acidic medium redox reactions, first calculate the change in oxidation numbers. The ratio of reactants is often obtained quickly by equating total electrons lost and gained before completing the full balancing process.
Updated On: Jun 11, 2026
  • \(6:5\)
  • \(6:4\)
  • \(1:1\)
  • \(5:4\)
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The Correct Option is A

Solution and Explanation

Step 1: Spot what is being oxidised and what is being reduced.
Let us look at the players. Manganese starts in $MnO_4^-$ and ends as $Mn^{2+}$, so its oxidation number falls. Iodine starts as $I^-$ and ends in $IO_3^-$, so its oxidation number rises. The one that falls is reduced (the oxidant), the one that rises is oxidised (the reductant).
Step 2: Count the change for manganese.
In $MnO_4^-$, oxygen is $-2$, so $x + 4(-2) = -1$ gives $x = +7$. In $Mn^{2+}$ it is $+2$. So manganese drops from $+7$ to $+2$, a gain of $5$ electrons per atom.
Step 3: Count the change for iodine.
In $I^-$ iodine is $-1$. In $IO_3^-$, $x + 3(-2) = -1$ gives $x = +5$. So iodine climbs from $-1$ to $+5$, a loss of $6$ electrons per atom.
Step 4: Use the simple electron-balance shortcut.
Instead of writing full half-reactions, just make total electrons lost equal total electrons gained. One $Mn$ gains $5$, one $I$ loses $6$. To match, multiply $Mn$ by the iodine's number and $I$ by the manganese's number. The least common multiple of $5$ and $6$ is $30$.
Step 5: Assign the coefficients.
We need $30$ electrons exchanged, so we need $\dfrac{30}{5} = 6$ manganese units and $\dfrac{30}{6} = 5$ iodide units. That gives $x = 6$ for $MnO_4^-$ and $y = 5$ for $I^-$.
Step 6: Sanity check with the full equation.
Plugging these in, the balanced reaction reads \[ 6MnO_4^- + 5I^- + 18H^+ \rightarrow 6Mn^{2+} + 5IO_3^- + 9H_2O \] Charge on the left is $6(-1)+5(-1)+18(+1) = +7$ and on the right $6(+2)+5(-1) = +7$, and atoms balance too. So the ratio we want is $x:y = 6:5$.
\[ \boxed{6:5} \]
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