Step 1: Defining Water of Crystallisation:
Water of crystallisation denotes water molecules chemically bonded within a compound's crystal structure, forming an essential part of its crystalline state.
Step 2: Examining Provided Compounds:
- FeSO4 (Iron(II) sulfate) can exist as hydrated FeSO4·7H2O, indicating 7 molecules of crystallisation water per molecule of compound.
- CuSO4 (Copper(II) sulfate) commonly forms CuSO4·5H2O, containing 5 molecules of crystallisation water.
- CaSO4 (Calcium sulfate) typically forms CaSO4·2H2O, with 2 molecules of crystallisation water.
- Na2CO3 (Sodium carbonate) forms Na2CO3·10H2O, containing 10 molecules of crystallisation water.
Step 3: Determination:
Of the compounds listed, FeSO4 forms a crystalline structure with 7 molecules of water of crystallisation per molecule of compound, the highest quantity among the given substances. Consequently, FeSO4 is the correct identification.