Question:medium

Consider an electron in the energy eigenstate \(\psi_{211}(\vec{r})\) of the hydrogen atom. Given that the radial probability distribution of the electron in such a state takes its maximum value at \(r = n_0 a\), where \(a\) is the Bohr radius, and \(n_0\) is an integer. The value of \(n_0\) (in integer) is . The radial part of the wavefunction \(\psi_{211}(\vec{r})\) is given by \(R_{21}(r) = \dfrac{1}{\sqrt{24a^{5}}}\,re^{-r/2a}\).

Show Hint

Hint:
\(P(r)=r^2R_{21}^2(r)\propto r^4e^{-r/a}\); maximize it by setting its derivative to zero, or by maximizing \(\ln[r^4e^{-r/a}]\).
Updated On: Jul 28, 2026
Show Solution

Correct Answer: 4

Solution and Explanation

Step 1: Simplify with a substitution before differentiating.
Let $x = r/a$, a dimensionless distance. Then the radial probability distribution becomes:
\[ P(r) \propto r^4 e^{-r/a} = a^4x^4 \cdot e^{-x} \]
Since $a^4$ is just a constant multiplier, maximizing $P$ over $r$ is the same as maximizing $g(x) = x^4e^{-x}$ over $x$.

Step 2: Use logarithmic differentiation instead of the product rule.
Take the natural log of $g(x)$ (valid for $x>0$, where $g>0$):
\[ \ln g(x) = 4\ln x - x \]
At a maximum, the derivative of $\ln g(x)$ is zero, since $\ln$ is an increasing function and $g$, $\ln g$ peak at the same $x$:
\[ \dfrac{d}{dx}\ln g(x) = \dfrac{4}{x} - 1 = 0 \]

Step 3: Solve for $x$ and convert back to $r$.
\[ \dfrac{4}{x} = 1 \implies x = 4 \]
Since $x=r/a$, this gives $r = 4a$. To confirm this is a maximum, check that $\ln g(x)$ is increasing for $x<4$ (since $4/x>1$ there) and decreasing for $x>4$ (since $4/x<1$ there), which is exactly the shape of a single peak.

Final Answer:
The radial probability distribution peaks at $r=4a$, so comparing with $r=n_0a$ gives $n_0=4$. \[ \boxed{n_0 = 4} \]
Was this answer helpful?
0